ASTM D4243-23

ASTM D4243-23

Standard Test Method for Measurement of Average Viscometric Degree of Polymerization of New and Aged Electrical Papers and Boards

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1.1 This test method describes a standard procedure for determining the average viscometric degree of polymerization (abbreviated Equation D4243-23_1) of new or aged electrical papers. The determination is made by measuring the intrinsic viscosity of a solution of the paper in an appropriate solvent.

1.2 The degree of polymerization (or the degree of condensation) of a particular cellulose molecule is the number of anhydro-ß-glucose monomers, C6H10O5, in the cellulose molecule. Within a sample of paper, not all the cellulose molecules have the same degree of polymerization so that the mean value measured by viscometric methods is not necessarily the same as that which are obtained by other methods.

1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. See Section 9.

1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.


Significance and Use:

5.1 This test method applies to all papers made from unmodified cellulose, as used in transformer, cable, or capacitor manufacture. It applies to new or aged papers. For information, Appendix X1 shows an example of statistical distribution of Equation D4243-23_2 values for new papers intended for the insulation of transformers, together with information relative to cable and capacitor papers. Nevertheless, where evaluating the decomposition stage of aged papers, take care to use, as a reference, the Equation D4243-23_3 value of the new paper of the very same origin, Equation D4243-23_4 of new papers being a function, among other factors, of their specific gravity and of their manufacturing process.

5.2 This test method can also be used for the determination of the intrinsic viscosity of solutions of chemically modified papers, provided that these dissolve completely in the selection solvent. Use this test method with caution when it is applied to papers with mineral fillers.

Additional Info

Author American Society for Testing and Materials (ASTM International)
Committee D09.01 - Committee D09 on Electrical and Electronic Insulating Materials
Published by ASTM
Document type Standard
Theme ,Paper and board insulating materials
ICS 29.035.10 : Paper and board insulating materials
Number of pages 7
Replace ASTM D4243-16
Set ASTM Volume 10.02 - Multi-User - Single-Site Online
Keyword D4243

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